Nei Ching

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The Nei Ching, which is reputed to have been written by the Yellow Emperor and to be the oldest medical book in existence, is the classic work on Chinese internal medicine, and it states that "Yin is active within and is a guardian of the Yang, whereas Yang is active on the outside and is the regulator of the Yin" — equating harmony of the Yin and Yang with health and constant youthfulness, and disharmony with ill health, disease or death.
The Taoist Art of K'ai Men Chapter 4